Tricresyl Phosphate|Flame Retardant TCP

First, Product Information
En Name Tricresyl Phosphate, Flame Retardant TCP,Tritolyl Phosphate
Chemical Formula C21H21O4P
Molecular Weight 368.36
CAS Registration Number 1330-78-5
EINECS Accession Number 215-548-8

Second, The Physical Information Of Tricresyl Phosphate, Flame Retardant TCP
Appearance: Transparent Liquid With Aromatic Odor
Flash Point: ≥225°C
Relative Density (20 ° C): 1.160-1.180;
Acid Value (MgKOH/G): ≤0.1
Free Phenol: ≤0.1%
Chromaticity (APHA): ≤50
Reduction After Heating: ≤0.1%
Melting Point (°C): -33
Boiling Point (°C): 410

Third, Product Technology
(1) Catalytic Synthesis Of Supported Heteropolyacid Salt
(1) Preparation Of Immobilized Heteropolyacid Salt Catalyst A Certain Amount Of TiC L4 Is Taken, Adjusted To PH 7-8 By Adding 12% Ammonia Water, Precipitated, Filtered And Washed Until Cl Ion Is Checked With 0.1 Mol/LAg NO 3 . Drying. The Above Raw Materials Are Reacted With A Certain Amount Of Pre-Heat Treated H4S IW12O40·ηH2O For 1.5 H. The Whole Process Solution Is Kept Near Boiling State, And The Water Is Slowly Distilled Off And Dried To Obtain A Catalyst Composed Of TiSiW12O40/Tio2.


(2) Synthesis The Quantitative Addition Of Cresol Was Added To The Reactor, And The Prepared TiSiW12O40/Tio2 Catalyst (1.0% Of The Total Amount Of Raw Materials) Was Stirred, Heated To 60 ° C, And Phosphorus Oxychloride Was Added Dropwise, And The Addition Was Completed Within About 1 H. The Temperature Was Raised To 100 ° C To Continue The Reaction, The Humidity Was Controlled At 100-120 ° C Until Substantially No HCI Evolution, The Reaction Was About 8 H. The Catalyst Was Filtered Off, And Then The Product Was Obtained By Distillation Under Reduced Pressure To Obtain A Product With A Yield Of About 85.5%.

(2) Indirect Method Of Phosphorus Trichloride (Cold Method) Mixing Cresol And Phosphorus Trichloride At 15-20 ° C To Form Tricresyl Phosphite, Then Introducing Chlorine Gas At 60-70 ° C To Form Dichloro Trimethyl Phosphite Is Further Hydrolyzed At 50 ° C To Form Tricresyl Phosphate. Finally, It Is Washed, Neutralized, Evaporated And Dehydrated And Distilled Under Reduced Pressure, And The Fraction Taken At 340-360 ° CkPa Is Taken As A Finished Product.
Purification Method: Separation Of Isomers Is Difficult, And Impurities Other Than Isomers Are Generally Removed By Distillation Under Reduced Pressure.

Fourth, Use:
1. This Product Is A Flame Retardant Plasticizer. It Is Compatible With Many Cellulose Resins, Vinyl Resins, Polystyrenes, Synthetic Rubbers, Especially With Polyvinyl Chloride, And Can Be Used As A Medium For Poor Compatibility And Improves Compatibility With Resins. This Product Has Good Compatibility, Flame Retardancy, Mildew Resistance, Abrasion Resistance, Stain Resistance, Weather Resistance, Radiation Resistance And Electrical Properties. This Product Is Used In Paint To Increase The Flexibility Of The Film. This Product Is Also Used As A Plasticizer For Synthetic Rubber And Viscose Fiber.
2. Used As A Flame Retardant Plasticizer For PVC Products Such As Cable Materials, Artificial Leather, Conveyor Belts, Sheets, Floor Materials, Etc. Also Used In Neoprene And Viscose. Further, Tricresyl Phosphate Is Also Used As A Flame Retardant Solvent For Water Repellents, Lubricants, And Nitrocellulose.
3. Used As Plastic Plasticizer And Spray Paint Plasticizer.

Five, Tricresyl Phosphate, Flame Retardant TCP Export Essential Information
Cas Number: 1330-78-5, UN:3082
Customs Code HS: 29199000.90
Tax Rebate: At Present, Tricresyl Phosphate, The Flame Retardant TCP Tax Rebate Is 9%.
Raw Materials: Using Phosphorus Trichloride And Mixed Cresol As Raw Materials.
It Belongs To Several Types Of Dangerous Goods: Currently Tricresyl Phosphate, Flame Retardant TCP Belongs To 9 Dangerous Goods.
Packing: Net Weight 200KG / Galvanized Iron Drum (16 Tons For A Small Cabinet), 1000KG / IB Barrel (18 Tons For A Small Cabinet) Or 23 Tons Of ISOTANK.